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ZDD - Giddings


This is the Zero Distortion Density (ZDD) inferred in all GenNLC models. This generalized normal's a1 center parameter is the mean or centroid of the Giddings density. The a2 is a dimensionless time constant which represents the lumped contributions to all band broadening that can be described by first order kinetics.

Peak

ZDD - GIDDINGS2.PNG

Cumulative

ZDD - GIDDINGS3.PNG

Reverse Cumulative

ZDD - GIDDINGS4.PNG

a0 = Area

a1 = Center (as mean of underlying Gaussian)

a2 = Width (as time constant)

The Giddings ZDD uses the above approximations. Modified Bessel functions and modified Bessel function integrals are not used.

Built-In Peak Model

  Gidx (Statistical family) Approximation
  Giddings (Chromatography family)
Full-Precision

User-Defined Peaks and View Functions

  Gidx(x,area,mean,Gidwidth) Giddings (Approximation)
  Giddings(x,area,center,width) Giddings (Full-Precision)

  Gidx_C(x,area,mean,Gidwidth) Giddings (Approximation) cumulative
  Gidx_CR(x,area,mean,Gidwidth) Giddings (Approximation) reverse cumulative

To use the full precision Giddings cumulatives and reverse cumulative, you will need the Bessel function integral:
  TFn(u,v) Modified Bessel Integral for NLC, Giddings CDF complement (u=a1/a2,v=x/a2)

This Giddings approximation is part of the unique content in the product covered by its copyright.



PeakLab v1 Documentation ZDD - [W] Chromatography Notes